Follow the steps here: https://www.nicksherlock.com/2022/10/installing-macos-13-ventura-on-proxmox/
To pass through an RX 6600:
Add PCI passthrough (must be raw device, not mapped)
Disable “Above 4G decoding” and “Resizeable BAR” in host BIOS
Add “agdpmod=pikera” as a boot argument in OpenCore
USB passthrough devices must have USB 3 enabled
Change SystemProductName to “MacPro7,1” to enable multi-display
Use
macserial to generate serial number and board serial and update them in config.plist